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<p>XML and RDF are the current standards for establishing semantic interoperability on the Web, but XML addresses only document structure. RDF better facilitates interoperation because it provides a data model that can be extended to address sophisticated ontology representation techniques.</p>
Michael Erdmann, Michel Klein, Dieter Fensel, Stefan Decker, Sergey Melnik, Jeen Broekstra, Frank Van Harmelen, Ian Horrocks, "The Semantic Web: The Roles of XML and RDF", IEEE Internet Computing, vol. 4, no. , pp. 63-74, September/October 2000, doi:10.1109/4236.877487
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