Along with the rapid development of information technology, one-to-one learning emerges. Research on the application of one-to-one learning in Chinese classical poem education is performed in this work using multi-dimensional methods. It is observed in our research that most learners can get accustomed to one-to-one learning mode, complete the expected learning contents and achieve preset goals. Further investigation and analysis are conducted on a small portion of the learners who are not willing to learn in one-to-one mode.