Afundamental problem in communication networks is wavelength assignment(WA): given a set of routing paths on a network, assign a wavelength to each path such that the paths with the same wavelength are edge-disjoint, using the minimum number of wavelengths. The WA problem is NP-hard for a tree of rings network which is well used in practice. In this paper, we give an efficient algorithm which solves the WA problem on a tree of rings with an arbitrary (node) degree by at most 3Lwavelengths and achieves an approximation ratio of 2.75 asymptotically, where L is the maximum number of paths on any link in the network. The 3L upper bound is tight that there are instances of theWAproblem that require at least 3L wavelengths even on a tree of rings with degree four. We also give a 3L and 2-approximation algorithm for the WA problem on a tree of rings with degree at most six. Previous results include: 4L (resp. 3L) wavelengths for trees of rings with arbitrary degrees (resp. degree at most eight), and 2-approximation (resp. 2.5-approximation) algorithm for trees of rings with degree four (resp. six).